Flow through macropores of different size classes in blanket peat     

Joseph Holden 《Journal of Hydrology》2009,364(3-4):342-348

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The effects of Hurricanes Katrina and Rita on seabed polycyclic aromatic hydrocarbon dynamics in the Gulf of Mexico     

Siddhartha Mitra  Joseph J. Lalicata  Mead A. Allison  Timothy M. Dellapenna 《Marine pollution bulletin》2009,58(6):851-857

To assess the extent to which Hurricanes Katrina and Rita affected polycyclic aromatic hydrocarbons (PAH) in the Gulf of Mexico (GOM), sediment cores were analyzed in late 2005 from: a shallow shelf, a deeper shelf, and a marsh station. Sediment geochronology, fabric, and geochemistry show that the 2005 storms deposited ∼10 cm of sediment to the surface of a core at 5-12A. Bulk carbon geochemistry and PAH isomers in this top layer suggest that the source of sediment to the top portion of core 5-12A was from a relatively more marine area. Particulate PAHs in the marsh core (04 M) appeared unaffected by the storms while sediments in the core from Station 5-1B (deeper shelf) were affected minimally (some possible storm-derived deposition). Substantial amounts of PAH-laden particles may have been displaced from the seabed in shallow areas of the water column in the GOM by these 2005 storms.  相似文献   

Seeing below the basalt – offshore Faroes     

Joseph W. Gallagher  Peter W. Dromgoole 《Geophysical Prospecting》2008,56(1):33-45

Exploration in the basalt covered areas of the Faroes offshore has always suffered from poor seismic imaging below the basalt. Long offset 2D and 3D seismic data were acquired and a significant improvement in the seismic image below top basalt has been achieved. Deep towing of the source and receiver cables helped by extending the seismic bandwidth towards lower frequencies. Bubble‐tuned rather than conventional peak‐tuned source arrays gave little, if any, incremental benefit. The improvement in the imaging comes primarily from the approach to processing the data. High frequencies (dominantly noise) are filtered out of the data early in the processing to concentrate on the low frequency data. Careful multiple removal is important with several passes of demultiple being applied to the data using both Surface‐Related Multiple Elimination (SRME) and Radon techniques. Velocity analysis is performed as an iterative process taking into account the geological model. Reprocessing legacy 2D surveys, acquired with wide‐ranging parameters, using these processing techniques improved these datasets significantly, indicating that sub‐basalt imaging seems to be more sensitive to processing than to the choice of acquisition parameters.  相似文献   

Sangay volcano, Ecuador: structural development, present activity and petrology     

Michel Monzier  Claude Robin  Pablo Samaniego  Minard L. Hall  Jo Cotten  Patricia Mothes  Nicolas Arnaud   《Journal of Volcanology and Geothermal Research》1999,90(1-2)

Sangay (5230 m), the southernmost active volcano of the Andean Northern Volcanic Zone (NVZ), sits 130 km above a >32-Ma-old slab, close to a major tear that separates two distinct subducting oceanic crusts. Southwards, Quaternary volcanism is absent along a 1600-km-long segment of the Andes. Three successive edifices of decreasing volume have formed the Sangay volcanic complex during the last 500 ka. Two former cones (Sangay I and II) have been largely destroyed by sector collapses that resulted in large debris avalanches that flowed out upon the Amazon plain. Sangay III, being constructed within the last avalanche amphitheater, has been active at least since 14 ka BP. Only the largest eruptions with unusually high Plinian columns are likely to represent a major hazard for the inhabited areas located 30 to 100 km west of the volcano. However, given the volcano's relief and unbuttressed eastern side, a future collapse must be considered, that would seriously affect an area of present-day colonization in the Amazon plain, 30 km east of the summit. Andesites greatly predominate at Sangay, there being few dacites and basalts. In order to explain the unusual characteristics of the Sangay suite—highest content of incompatible elements (except Y and HREE) of any NVZ suite, low Y and HREE values in the andesites and dacites, and high Nb/La of the only basalt found—a preliminary five-step model is proposed: (1) an enriched mantle (in comparison with an MORB source), or maybe a variably enriched mantle, at the site of the Sangay, prior to Quaternary volcanism; (2) metasomatism of this mantle by important volumes of slab-derived fluids enriched in soluble incompatible elements, due to the subduction of major oceanic fracture zones; (3) partial melting of this metasomatized mantle and generation of primitive basaltic melts with Nb/La values typical of the NVZ, which are parental to the entire Sangay suite but apparently never reach the surface and subordinate production of high Nb/La basaltic melts, maybe by lower degrees of melting at the periphery of the main site of magma formation, that only infrequently reach the surface; (4) AFC processes at the base of a 50-km-thick crust, where parental melts pond and fractionate while assimilating remelts of similar basaltic material previously underplated, producing andesites with low Y and HREE contents, due to garnet stability at this depth; (5) low-pressure fractionation and mixing processes higher in the crust. Both an enriched mantle under Sangay prior to volcanism and an important slab-derived input of fluids enriched in soluble incompatible elements, two parameters certainly related to the unique setting of the volcano at the southern termination of the NVZ, apparently account for the exceptionally high contents of incompatible elements of the Sangay suite. In addition, the low Cr/Ni values of the entire suite—another unique characteristic of the NVZ—also requires unusual fractionation processes involving Cr-spinel and/or clinopyroxene, either in the upper mantle or at the base of the crust.  相似文献   

Uranium Removal from Ground Water Using Zero Valent Iron Media   总被引：1，自引：0，他引：1  

James Farrell  William D. Bostick  Robert J. Jarabek  Joseph N. Fiedor 《Ground water》1999,37(4):618-624

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Baseline Sediment Trace Metals Investigation: Steinhatchee River Estuary, Florida, Northeast Gulf of Mexico     

Candace A. Trimble  Ronald W. Hoenstine  A. Brad Highley  Joseph F. Donoghue  Paul C. Ragland 《Marine Georesources & Geotechnology》1999,17(2):187-197

This Florida Geological Survey U.S. Department of the Interior, Minerals Manage ment Service Cooperative Study provides baseline data for major and trace metal concentrations in the sediments of the Steinhatchee River estuary. These data are intended to provide a benchmark for comparison with future metal concentration data measurements. The Steinhatchee River estuary is a relatively pristine bay located within the Big Bend Wildlife Management Area on the North Central Florida Gulf of Mexico coastline. The river flows 55 km through woodlands and planted pines before emptying into the Gulf at Deadman Harbor. Water quality in the estuary is excellent at present. There is minimal development within the watershed. The estuary is part of an extensive system of marshes that formed along the Florida Gulf coast during the Holocene marine transgression. Sediment accretion rate measurements range from 1.4 to 4.1 mm yr on the basis of lead-210 measurements. Seventy-nine short cores were collected from 66 sample locations, representing four lithofacies: clay- and organic-rich sands, organic-rich sands, clean quartz sands, and oyster bioherms. Samples were analyzed for texture, total organic matter, total carbon, total nitrogen, clay mineralogy, and major and trace-metal content. Follow ing these analyses, metal concentrations were normalized against geochemical reference elements (aluminum and iron) and against total weight percent organic matter. Metals were also normalized granulometrically against total weight percent fines (0.062 mm). Concentrations were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) for all metals except mercury. Mercury concentrations were determined by cold-flameless atomic absorption spectrometry (AAS). Granulo metric measurements were made by sieve and pipette analyses. Organic matter was determined by two methods: weight loss upon ignition and elemental analysis (by Carlo-Erba Furnace) of carbon and nitrogen. X-ray diffraction was used to deter mine clay mineralogy. Trace-metal concentrations were best correlated when normalized with respect to sediment aluminum concentrations. Normalizations indicate that most major and trace-metal concentrations fall within 95 % prediction limits of the expected value. This finding suggests that little significant metal contamination occurred within this system prior to 1994 sediment sampling. Exceptions include lead, mercury, copper, zinc, potassium, and phosphorous. Lead and mercury are elements that generally enter this watershed through atmospheric deposition; thus, anomalous levels of these metals are not necessarily associated with activities within the watershed of the Steinhatchee River estuary. Anomalous concentrations of other metals such as zinc, copper, and phosphorous probably do originate within the Steinhatchee watershed. Copper failed to correlate well with any geochemical or granulometric normalizer, and this condition was not limited to a single facies or area within the estuary. This finding may indicate copper contamination in the system. Increased zinc and copper levels may be attributed to marine paints. Phosphorous levels also appeared to be elevated in a few locations in the two marsh facies sampled. This may be due to nutrient loading from two small communities, Jena and Steinhatchee, or from the application of this element in fertilizer to reduce moisture stress to young planted pines on tree farms within the watershed.  相似文献   

Yanshanian and Himalayan Evolution of the Western Tarim Area(Xinjiang China): From the Jurassic Trough up to the Neogere and Quaternary Flexural Basin     

Joseph CANEROT  et al 《地学前缘》2000,(Z1)

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Early diagenetic alteration of chlorophyll-a and bacteriochlorophyll-a in a contemporaneous marl ecosystem; Florida Bay     

J. William Louda  Joseph W. Loitz  David T. Rudnick  Earl W. Baker 《Organic Geochemistry》2000,31(12)

This report covers the analyses of tetrapyrrole pigments in sediments and numerous source biota from northern central Florida Bay. Sediment cores were all carbonate marls and ‘bedrock’ (Pleistocene limestones) was typically at 0.6–1.2 m bsf. (below sea floor). Extraction of the sediments was performed using tetrahydrofuran, shown to be 3–7 times as effective as more common solvents. Surficial sediments were found to contain a pigment distribution indicating a diatomaceous-cyanobacterial biofilm/mat underlain with purple sulfur bacteria as the microphytobenthos. Downhole trends in pigment diagenesis revealed differences due to paleoenvironment. That is, when bacteriochlorophyll-a (BCHLa) plus derivatives were elevated, indicating strong syn-depositional anoxia, the pheophytins-a (PTINsa) were the major chlorophyll-a (CHLa) derivatives. Conversely, when BCHL-a plus derivatives were low, indicating oxic to dys-oxic syn-depositional conditions, then pyropheophorbide-a (pPBIDa) and 13², 17²-cyclopheophorbide-a (CYCLO) were strongly dominant. The generation of cyclopheophorbide in carbonate marls with weakly anoxic to dysoxic syn-depositional conditions may yield an oil-source paleoenvironmental marker for bitumen containing compounds such as bicycloalkanoporphyrins (BiCAPs). Downhole conversions were observed for the following diagenetic steps; CHLa to pheophytin-a (PTINa), PTINa to pyropheophytin-a (pPTINa), pPBIDa to CYCLO, BCHLa to bacteriopheophytin-a (BPTINa), and BPTINa to bacteriopyropheophytin-a (BpPTINa).  相似文献   

A new strategy for analyzing the chronometry of constructed rock features in deserts     

Niccole Villa Cerveny  Russell Kaldenberg  Judyth Reed  David S. Whitley  Joseph Simon  Ronald I. Dorn 《Geoarchaeology》2006,21(3):281-303

The western Great Basin contains thousands of constructed rock features, including rock rings, cairns, and alignments. Unlike subtractive geoglyphs, such as the Nasca Lines of Peru, that remove desert pavement, these surface features alter the location and positioning of cobble‐ to bouldersized rocks. The chronology of surface rock features has remained unconstrained by numerical ages because no prior chronometric approach has been able to yield age control. We propose a new strategy for studying these features by analyzing anthropogenic modifications to rock coatings, an approach that permits the use of several dating methods, two of which are assessed here: radiocarbon dating of pedogenic carbonate and rock‐varnish microlaminations. Initial results from Searles Valley, eastern California, suggest that constructed rock features may be as old as early Holocene and terminal Pleistocene. Archaeological surveys of desert areas would be greatly enhanced if they noted altered positions of rock coatings. © 2006 Wiley Periodicals, Inc.  相似文献   

Fluctuations in isothermal spheres     

Joseph Katz  Isao Okamoto 《Monthly notices of the Royal Astronomical Society》2000,317(1):163-169

Isolated isothermal spheres of N gravitationally interacting points with equal mass are believed to be stable when density contrasts do not exceed 709. That stability limit does not, however, take into consideration fluctuations of temperature near the onset of instability. These are important when N is finite.
Here we correlate global mean quadratic temperature fluctuations with the onset of instability. We show that such fluctuations trigger instability when the density contrast reaches a value near 709×exp(−3.3 N ^−1/3). These lower values of limiting density contrasts are significantly smaller than 709 when N is not very large, and this suggests (i) that numerical calculations with small N may not reflect correctly the onset of core collapse in clusters with large N , and (ii) that a greater number of globular clusters than is normally believed may already be in an advanced stage of core collapse, because most of the observed globular clusters with parameters that fit quasi-isothermal configurations are close to marginal stability.  相似文献